The Determination of Chlorinated o-Cresols and Chlorinated o-Tolyloxyacetic Acids.

O-Methylation of Chlorinated para-Hydroquinones by Rhodococcus chlorophenolicus.

Rhodococcus chlorophenolicus PCP-I, a degrader of polychlorinated phenols, guaiacols (2-methoxyphenols), and syringols (2,6-dimethoxyphenols), was shown to O-methylate the degradation intermediate, a chlorinated para-hydroquinone, into 4-methoxyphenol. O-methylation was constitutively expressed, whereas the degradation of chlorophenols and chlorohydroquinones was inducible in R. chlorophenolicu...

Aerobic degradation of mixtures of chlorinated aliphatics by cloned toluene-o-xylene monooxygenase and toluene o-monooxygenase in resting cells.

Recombinant strains of Escherichia coli constitutively expressing toluene-o-xylene monooxygenase (ToMO) of Pseudomonas stutzeri OX1 and toluene o-monooxygenase (TOM) of Burkholderia cepacia G4 were investigated for their ability to oxidize trichloroethylene (TCE), 1,1-dichloroethylene (1,1-DCE), cis-1,2-dichloroethylene (cis-DCE), trans-1,2-dichloroethylene (trans-DCE), vinyl chloride (VC), and...

Biodegradability of chlorinated solvents and related chlorinated aliphatic compounds

Synthesis, characterization and enzyme inhibition study of O-substituted derivatives of chlorinated coumarin.

Coumarins have much importance in dyes, drugs, perfumes and pesticides. In the demonstrated research work, a benignant series of chlorinated coumarins was synthesized and screened against different enzymes. First, 6-Chloro-7-hydroxy-4-methyl-2H-chromen-2-one (3) was geared up by the reaction of 4-chlororesorcinol (1) and ethyl acetoacetate (2) in the presence of concentrated H(2)SO(4). Second, ...

Chlorinated solvents